Systems and Methods for Detection of Plasma Instability by Optical Diagnosis

ABSTRACT

A wafer is positioned on a wafer support apparatus beneath an electrode such that a plasma generation region exists between the wafer and the electrode. Radiofrequency power is supplied to the electrode to generate a plasma within the plasma generation region. Optical emissions are collected from the plasma using one or more optical emission collection devices, such as optical fibers, charge coupled device cameras, photodiodes, or the like. The collected optical emissions are analyzed to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions. Upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, at least one plasma generation parameter is adjusted to mitigate formation of the plasma instability.

CLAIM OF PRIORITY

This application claims priority under 35 U.S.C. 119(e) to U.S. Provisional Patent Application No. 62/256,682, filed Nov. 17, 2015, the disclosure of which is incorporated herein by reference in its entirety for all purposes.

BACKGROUND 1. Field of the Invention

The present invention relates to semiconductor device fabrication.

2. Description of the Related Art

Many modern semiconductor chip fabrication processes include generation of a plasma from which ions and/or radical constituents are derived for use in either directly or indirectly affecting a change on a surface of a wafer exposed to the plasma. For example, various plasma-based processes can be used to etch material from a wafer surface, deposit material onto a wafer surface, or modify a material already present on a wafer surface. The plasma is often generated by applying radiofrequency (RF) power to a process gas in a controlled environment, such that the process gas becomes energized and transforms into the desired plasma. The characteristics of the plasma are affected by many process parameters including, but not limited to, material composition of the process gas, flow rate of the process gas, geometric features of the plasma generation region and surrounding structures, temperatures of the process gas and surrounding materials, frequency and magnitude of the RF power applied, and bias voltage applied to attract charged constituents of the plasma toward the wafer, among others.

However, in some plasma processes, the above-mentioned process parameters may not provide for adequate control of all plasma characteristics and behavior. In particular, in some plasma processes, an instability referred to as a “plasmoid” may occur within the plasma, where the plasmoid is characterized by a small area of higher density plasma surrounded by larger volumes of normal density plasma. The formation of plasmoids can lead to non-uniformity in the processing results on the wafer. Therefore, it is of interest to detect plasmoid formation, so as to enable mitigating and/or corrective action. It is within this context that the present invention arises.

SUMMARY

In an example embodiment, a method is disclosed for plasma processing of a wafer. The method includes positioning a wafer on a wafer support apparatus. The wafer support apparatus is positioned beneath an electrode such that a plasma generation region exists between the wafer and the electrode. The method also includes supplying radiofrequency power to the electrode to generate a plasma within the plasma generation region. The method also includes collecting optical emissions from the plasma using one or more optical emission collection devices. The method also includes analyzing the collected optical emissions to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions. The method also includes adjusting at least one plasma generation parameter to mitigate formation of the plasma instability, upon determining that the optical signature of the plasma instability does exist in the collected optical emissions.

In an example embodiment, a system is disclosed for plasma processing of a wafer. The system includes a wafer support apparatus configured to support a wafer during a plasma processing operation. The system also includes an electrode positioned above the wafer support apparatus so as to form a plasma generation region between the electrode and the wafer support apparatus. The system also includes a radiofrequency power supply connected to deliver radiofrequency power to the electrode. The system also includes at least one optical emission collection device disposed to collect optical emissions from a plasma to be generated within the plasma generation region. The system also includes an optical signal processing unit configured to analyze optical emissions collected by the at least one optical emission collection device to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions. The optical signal processing unit is configured to provide notification of determining that the optical signature of the plasma instability does exist in the collected optical emissions.

Other aspects and advantages of the invention will become more apparent from the following detailed description, taken in conjunction with the accompanying drawings, illustrating by way of example the present invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1A shows a wafer processing system, in accordance with some embodiments of the present invention.

FIG. 1B shows a wafer processing system, in accordance with some embodiments of the present invention.

FIG. 2 shows a top view of a multi-station processing tool that includes four processing stations, in accordance with some embodiments of the present invention.

FIG. 3 shows a schematic view of an embodiment of the multi-station processing tool interfaced with an inbound load lock and an outbound load lock, in accordance with some embodiments of the present invention.

FIG. 4 shows an example of the pedestal configured to receive the wafer for a deposition process, in accordance with some embodiments of the present invention.

FIG. 5A shows a vertical cross-section view of the pedestal, in accordance with some embodiments of the present invention.

FIG. 5B shows a close-up view of the region 501 referenced in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 5C also shows a close-up view of the region 501 referenced in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 5D also shows a close-up view of the region 503 referenced in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 5E also shows a close-up view of the region 503 referenced in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 5F shows a top view of the electrically conductive layer corresponding to referenced view A-A as identified in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 5G shows a top view of the electrically conductive layer corresponding to referenced view A-A as identified in FIG. 5A, in accordance with some embodiments of the present invention.

FIG. 6 shows a schematic of DC electrical current flow from the DC power supply through the chamber, in accordance with some embodiments of the present invention.

FIG. 7 shows an alternate schematic of DC electrical current flow from the DC power supply through the chamber, in accordance with some embodiments of the present invention.

FIG. 8 shows a flowchart of a method for plasma processing of a wafer, in accordance with some embodiments of the present invention.

FIG. 9 shows an example optical emission spectra of an argon/oxygen plasma, in accordance with some embodiments of the present invention.

FIG. 10 shows a plot of the ratio of intensity of optical emission observed with and without plasmoid formation, in accordance with some embodiments of the present invention.

FIG. 11 shows a plot of normalized optical emission intensity as a function of applied RF power, in accordance with some embodiments of the present invention.

FIG. 12 shows a wafer processing system having various optical emission collection devices configured to collect optical emission data from the plasma for processing by an optical signal processing unit, in accordance with some embodiments of the present invention.

FIG. 13 shows a flowchart of a method for plasma processing of a wafer, in accordance with some embodiments of the present invention.

DETAILED DESCRIPTION

In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be apparent, however, to one skilled in the art that the present invention may be practiced without some or all of these specific details. In other instances, well known process operations have not been described in detail in order not to unnecessarily obscure the present invention.

Deposition of films can be implemented in a plasma enhanced chemical vapor deposition (PECVD) system. The PECVD system may take many different forms. The PECVD system includes one or more chambers or “reactors” (sometimes including multiple stations) that house one or more wafers and are suitable for wafer processing. Each chamber may house one or more wafers for processing. The one or more chambers maintain the wafer in a defined position or positions (with or without motion within that position, e.g. rotation, vibration, or other agitation). A wafer undergoing deposition may be transferred from one station to another within a reactor chamber during the process. Of course, the film deposition may occur entirely at a single station or any fraction of the film may be deposited at any number of stations. While in process, each wafer is held in place by a pedestal, wafer chuck and/or other wafer holding apparatus. For certain operations, the apparatus may include a heater such as a heating plate to heat the wafer.

In an example embodiment, the term wafer as used herein refers to a semiconductor wafer. Also, in various embodiments, the wafer as referred to herein may vary in form, shape, and/or size. For example, in some embodiments, the wafer as referred to herein may correspond to a 200 mm (millimeters) semiconductor wafer, a 300 mm semiconductor wafer, or a 450 mm semiconductor wafer. Also, in some embodiments, the wafer as referred to herein may correspond to a non-circular substrate, such as a rectangular substrate for a flat panel display, or the like, among other shapes.

FIG. 1A illustrates a wafer processing system 100, which is used to process a wafer 101, in accordance with some embodiments of the present invention. The system includes a chamber 102 having a lower chamber portion 102 b and an upper chamber portion 102 a. A center column 141 is configured to support a pedestal 140 formed of an electrically conductive material. The electrically conductive pedestal 140 is connected to receive RF signals from an RF power supply 104 by way of a match network 106, depending on a setting of an RF direction control module 250. Also, in the wafer processing system 100 of FIG. 1A, a showerhead electrode 150 is configured and connected to receive RF signals from the RF power supply 104 by way of the match network 106, depending on the setting of the RF direction control module 250. In some embodiments, the RF direction control module 250 is configured to direct RF signals transmitted from the RF power supply 104 by way of the match network 106 to either the showerhead electrode 150 or to the pedestal 140. Also, the RF direction control module 250 is configured to electrically connect whichever one of the showerhead electrode 150 and the pedestal 140 that is not currently receiving RF signals to a reference ground potential. In this manner, at a given time, the RF direction control module 250 operates to ensure that either the showerhead electrode 150 will receive RF signals from the RF power supply 104 while the pedestal 140 is electrically connected to the reference ground potential, or the pedestal 140 will receive RF signals from the RF power supply 104 while the showerhead electrode 150 is electrically connected to the reference ground potential.

The RF power supply 104 is controlled by a control module 110, e.g., a controller. The control module 110 is configured to operate the wafer processing system 100 by executing process input and control instructions/programs 108. The process input and control instructions/programs 108 may include process recipes, having directions for parameters such as power levels, timing parameters, process gases, mechanical movement of the wafer 101, etc., such as to deposit or form films over the wafer 101.

In some embodiments, the center column 141 can include lift pins, which are controlled by lift pin control 122. The lift pins are used to raise the wafer 101 from the pedestal 140 to allow an end-effector to pick up the wafer 101, and to lower the wafer 101 after being placed by the end-effector. The wafer processing system 100 further includes a gas supply system 112 that is connected to process gas supplies 114, e.g., gas chemistry supplies from a facility. Depending on the processing being performed, the control module 110 controls the delivery of process gases 114 via the gas supply system 112. The chosen process gases are then flowed into the showerhead electrode 150 and distributed in a processing volume defined between the showerhead electrode 150 and the wafer 101 disposed upon the pedestal 140.

Further, the process gases may be premixed or not. Appropriate valving and mass flow control mechanisms may be employed within the gas supply system 112 to ensure that the correct process gases are delivered during the deposition and plasma treatment phases of the process. Process gases exit the processing volume and flow through an exhaust outlet 143. A vacuum pump (such as a one or two stage mechanical dry pump, among other types) draws process gases out of the processing volume and maintains a suitably low pressure within the processing volume by a closed loop feedback controlled flow restriction device, such as a throttle valve or a pendulum valve.

Also shown is a carrier ring 200 that encircles an outer region of the pedestal 140. The carrier ring 200 is configured to support the wafer 101 during transport of the wafer 101 to or from the pedestal 140. The carrier ring 200 is configured to sit over a carrier ring support region that is a step down from a wafer support region in the center of the pedestal 140. The carrier ring 200 has an annular shaped disc structure and includes an outer edge side of its disc structure, e.g., outer radius, and a wafer edge side of its disc structure, e.g., inner radius, that is closest to where the wafer 101 sits. The wafer edge side of the carrier ring 200 includes a plurality of contact support structures which are configured to lift the wafer 101 when the carrier ring 200 is lifted by spider forks 180. The carrier ring 200 is therefore lifted along with the wafer 101 and can be rotated to another station, e.g., in a multi-station system. Carrier ring lift and/or rotate control signals 124 are generated by the control module 110 to control operation of the spider forks 180 to lift and/or rotate the carrier ring 200.

In some embodiments, the electrical insulating layer 507 is disposed on a top surface of the pedestal 140, and an electrically conductive layer 509 is disposed on the electrically insulating layer 507. The electrically conductive layer 509 is configured to support the wafer 101. Also, in these embodiments, the electrically conductive layer can be electrically connected to a positive terminal of a direct current (DC) power supply 521 by way of a low pass filter 525. The DC power supply 521 is also connected to be controlled by the control module 110. Therefore, in some embodiments, electrical current can be transmitted from the DC power supply 521 through the low pass filter 525 to the electrically conductive layer 509, in accordance with a prescribed recipe as provided by the process input and control instructions/programs 108 and as executed by the control module 110.

FIG. 1B illustrates a wafer processing system 100A that is configured to perform an atomic layer deposition (ALD) process on the wafer 101 (e.g. an ALD oxide process), in accordance with some embodiments of the present invention. Similar componentry as described with regard to FIG. 1A is shown in FIG. 1B. Specifically, the wafer processing system 100A also includes the upper chamber portion 102 a, the lower chamber portion 102 b, the control module 110, the RF power supply 104, the match network 106, the electrically conductive layer 509, the DC power supply 521, the low pass filter 525, the carrier ring 200, and the spider forks 180. In the wafer processing system 100A, a pedestal 140A is configured to include a dielectric body 251. In some embodiments, the dielectric body 251 is affixed directly to the column 141. And, in some embodiments, the dielectric body 251 is supported by a conductive structure 252 that is affixed to the column 141. The electrically conductive layer 509 is disposed directly upon a top surface of the dielectric body 251 of the pedestal 140A.

In some embodiments, a heating component 253, such as a resistance heating element, is disposed with the dielectric body 251 of the pedestal 140A. The heating component 253 is connected to a heater power supply 255, which is in turn connected to the control module 110. With the heating component 253 present, in some embodiments, the heater power supply 255 can be operated in accordance with a prescribed recipe as provided by the process input and control instructions/programs 108 and as executed by the control module 110. It should also be understood that temperature measurement devices can be installed on/within the pedestal 140A and/or at other locations around the pedestal 140A to provide temperature measurement data to the control module 110, thereby enabling operation of a closed-loop temperature feedback control circuit between the control module 110 and the heater power supply 255.

The dielectric body 251 of the pedestal 140A includes an RF electrode 254 configured and connected to receive RF signals from the RF power supply 104 by way of the match network 106, depending on the setting of an RF direction control module 250. Also, in the wafer processing system 100A of FIG. 1B, a showerhead electrode 150A is configured and connected to receive RF signals from the RF power supply 104 by way of the match network 106, depending on the setting of the RF direction control module 250. In some embodiments, the RF direction control module 250 is configured to direct RF signals transmitted from the RF power supply 104 by way of the match network 106 to either the showerhead electrode 150A or to the RF electrode 254. Also, the RF direction control module 250 is configured to electrically connect whichever one of the showerhead electrode 150A and the RF electrode 254 that is not currently receiving RF signals to a reference ground potential. In this manner, at a given time, the RF direction control module 250 operates to ensure that either the showerhead electrode 150A will receive RF signals from the RF power supply 104 while the RF electrode 154 is electrically connected to the reference ground potential, or the RF electrode 154 will receive RF signals from the RF power supply 104 while the showerhead electrode 150A is electrically connected to the reference ground potential.

FIG. 2 shows a top view of a multi-station processing tool 300 that includes four processing stations, in accordance with some embodiments of the present invention. This top view is of the lower chamber portion 102 b (e.g., with the top chamber portion 102 a removed for illustration). The four processing stations are accessed by spider forks 180. Each spider fork 180, or fork, includes a first and second arm, each of which is positioned around a portion of each side of the pedestal 140/140A. The spider forks 180, using an engagement and rotation mechanism 220 are configured to raise up and lift the carrier rings 200 (i.e., from a lower surface of the carrier rings 200) from the processing stations in a simultaneous manner, and then rotate a distance of at least one or more stations before lowering the carrier rings 200 (where at least one of the carrier rings supports a wafer 101) so that further plasma processing, treatment and/or film deposition can take place on respective wafers 101.

FIG. 3 shows a schematic view of an embodiment of the multi-station processing tool 300 interfaced with an inbound load lock 302 and an outbound load lock 304, in accordance with some embodiments of the present invention. A robot 306, at atmospheric pressure, is configured to move wafers 101 from a cassette loaded through a pod 308 into inbound load lock 302 via an atmospheric port 310. Inbound load lock 302 is coupled to a vacuum source/pump so that, when atmospheric port 310 is closed, inbound load lock 302 may be pumped down. Inbound load lock 302 also includes a chamber transport port 316 interfaced with processing chamber 102. Thus, when chamber transport 316 is opened, another robot 312 may move the wafer from inbound load lock 302 to the pedestal 140/140A of a first process station for processing.

The depicted processing chamber 102 comprises four process stations, numbered from 1 to 4 in the example embodiment shown in FIG. 3. In some embodiments, processing chamber 102 may be configured to maintain a low pressure environment so that wafers may be transferred using the carrier ring 200 among the process stations 1-4 without experiencing a vacuum break and/or air exposure. Each process station 1-4 depicted in FIG. 3 includes a pedestal 140/140A and showerhead electrode 150/150A and associated process gas supply connections. Also, it should be understood that in other embodiments the processing chamber 102 can include less than four process stations or more than four process stations.

FIG. 3 also shows the spider forks 180 for transferring wafers within the processing chamber 102. As mentioned above, the spider forks 180 rotate and enable transfer of wafers from one processing station to another. The transfer occurs by enabling the spider forks 180 to lift the carrier rings 200 from an outer undersurface, which lifts the wafers 101, and rotates the wafers 101 and carrier rings 200 together to the next processing station. In one configuration, the spider forks 180 are made from a ceramic material to withstand high levels of heat during processing.

FIG. 4 shows an example of the pedestal 140/140A configured to receive the wafer 101 for a deposition process, such as an atomic layer deposition (ALD) process, in accordance with some embodiments of the present invention. The pedestal 140/140A includes the electrically conductive layer 509 positioned on a central top surface of the pedestal 140/140A, where the central top surface is defined by a circular area extending from a central axis 420 of the pedestal 140/140A to a top surface diameter 422 that defines the edge of the central top surface. The electrically conductive layer 509 includes a plurality of wafer supports 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f, which are distributed across the electrically conductive layer 509 and which are configured to support the wafer 101. A wafer support level is defined by the vertical position of the bottom surface of the wafer 101 when seated on the wafer supports 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f. In the example of FIG. 4, there are six wafer supports 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f symmetrically distributed about a periphery of the electrically conductive layer 509. However, in other embodiments there may be any number of wafer supports on the electrically conductive layer 509, and the wafer supports can be distributed across the electrically conductive layer 509 in any suitable arrangement for supporting the wafer 101 during deposition process operations. FIG. 4 also shows recesses 406 a, 406 b, and 406 c, which are configured to house lift pins. The lift pins can be utilized to raise the wafer 101 from the wafer supports 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f to allow for engagement of the wafer 101 by an end-effector.

In some embodiments, each wafer support 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f defines a minimum contact area structure (MCA). MCA's are used to improve precision mating between surfaces when high precision or tolerances are required, and/or minimal physical contact is desirable to reduce defect risk. Other surfaces in the system can also include MCA's, such as over the carrier ring 200 supports, and over the inner wafer support region of the carrier ring 200.

The pedestal 140/140A further includes an annular surface 410 extending from the top surface diameter 422 of the pedestal 140/140A to an outer diameter 424 of the annular surface 410. The annular surface 410 defines an annular region surrounding the electrically conductive layer 509, but at a step down from the electrically conductive layer 509. That is, the vertical position of the annular surface 410 is lower than the vertical position of the electrically conductive layer 509. A plurality of carrier ring supports 412 a, 412 b, and 412 c are positioned substantially at/along the edge (outer diameter) of the annular surface 410 and are symmetrically distributed about the annular surface 410. The carrier ring supports can in some embodiments define MCA's for supporting the carrier ring 200. In some implementations, the carrier ring supports 412 a, 412 b, and 412 c extend beyond the outer diameter 424 of the annular surface 410, whereas in other implementations they do not. In some implementations, the top surfaces of the carrier ring supports 412 a, 412 b, and 412 c have a height that is slightly higher than that of the annular surface 410, so that when the carrier ring 200 is resting on the carrier ring supports 412 a, 412 b, and 412 c, the carrier ring 200 is supported at a predefined distance above the annular surface 410. Each carrier ring support 412 a, 412 b, and 412 c may include a recess, such as recess 413 of carrier ring support 412 a, in which an extension protruding from the underside of the carrier ring 200 is seated when the carrier ring 200 is supported by the carrier ring supports 412 a, 412 b, and 412 c. The mating of the carrier ring extensions to the recesses (413) in the carrier ring supports 412 a, 412 b, and 412 c provides for secure positioning of the carrier ring 200 and prevents the carrier ring 200 from moving when seated on the carrier ring supports 412 a, 412 b, and 412 c.

In some implementations, the top surfaces of the carrier ring supports 412 a, 412 b, and 412 c are flush with the annular surface 410. In other implementations, there are no carrier ring supports separately defined from the annular surface 410, so that the carrier ring 200 may rest directly on the annular surface 410, and such that no gap exists between the carrier ring 200 and the annular surface 410. In such implementations, a pathway between the carrier ring 200 and the annular surface 410 is closed, preventing precursor materials from reaching a backside/underside of the wafer 101 via this pathway.

In the example embodiment of FIG. 4, there are three carrier ring supports 412 a, 412 b, and 412 c positioned symmetrically along the outer edge region of the annular surface 410. However, in other implementations, there may be more than three carrier ring supports, distributed at any locations along the annular surface 410 of the pedestal 140/140A, to support the carrier ring 200 in a stable resting configuration.

When the wafer 101 is supported by the wafer supports 404 a, 404 b, 404 c, 404 d, 404 e, and 404 f, and when the carrier ring 200 is supported by the carrier ring supports 412 a, 412 b, and 412 c, an edge region of the wafer 101 is disposed over an inner portion of the carrier ring 200. Generally speaking, the edge region of the wafer 101 extends from an outer edge of the wafer 101 inward by about 2 millimeters (mm) to about 5 mm. A vertical separation is thereby defined between the edge region of the wafer 101 and the inner portion of the carrier ring 200. In some embodiments, this vertical separation is about 0.001 inch to about 0.010 inch. The support of the carrier ring 200 at the predefined distance above the annular surface 410 and the vertical separation between the edge region of the wafer 101 and the inner portion of the carrier ring 200, can be controlled to limit deposition on a backside/underside of the wafer 101 in the edge region of the wafer 101.

Some plasmas used to deposit thin films or to treat the wafer surface are unstable under conditions that are preferred from a process standpoint. As an example, Ar/O2 capacitively-coupled-plasma (CCP) discharge operated within a 1 to 3 Torr pressure range and at high RF power (>200 W per 300 mm diameter wafer processing station) shows instabilities within the plasma. One such plasma instability, referred to herein as a “plasmoid” is characterized by small areas of higher density (brighter) plasma surrounded by larger volumes of normal density plasma. When plasmoids are formed, the deposited film is locally densified near the plasmoid due to interaction of the film with the local high density plasma corresponding to the plasmoid, which results in degraded film uniformity. A spatial distribution of plasmoids over the wafer 101 can vary from process-to-process, and within a given process. Also, the plasmoids can move across the wafer 101 during a given process. It should be understood that the plasmoids cause a degradation in process uniformity across the wafer 101, such as by changing a thickness of a deposited film at different locations across the wafer 101. The non-uniformity in film thickness caused by the plasmoids can be about 1% to 2% of the total film thickness, which can be significant in some applications that require an ultra-flat film profile.

During an example film deposition process, an operation is performed to apply a monolayer of a precursor gas, without applying any RF power. The precursor gas sticks to the wafer 101. In some embodiments, the precursor gas includes silicon to enable formation of silicon oxide on the wafer. An operation is then performed to flush the precursor gas from the processing volume over the wafer 101, thereby leaving the monolayer of the precursor gas on the wafer 101. An oxidation process is then performed on the wafer 101. In the oxidation process, a process gas is flowed into the processing volume over the wafer 101 and RF power is applied to the process gas to generate a plasma within the processing volume. The plasma drives oxidation reactions on the wafer 101. In some embodiments, the process gas will contain oxygen plus one or more other bombardment gases, such as argon, among others, where the bombardment gas(es) provide sufficient densification of the plasma. The bombardment gas is a gas that is effective in densifying a deposited film. Bombardment gases that densify the deposited film are those gases that can effectively transfer energy to the deposited film. In some embodiments, the bombardment gases are monoatomic noble gases, such as argon, among others, that do not react chemically with the deposited film and that lack vibrational or rotational molecular modes. For instance, in an example process, the process gas mixture can include about 5% to about 20% oxygen with the balance of the process gas mixture being argon. And, in other example processes, the percentage of oxygen to the bombardment gas in the process gas mixture can be less than 5% or greater than 20%.

During the oxidation process, when a particular thickness of film is formed on the wafer 101, the plasmoids may begin to appear across the wafer 101. The number and size of the plasmoids has a direct correlation with the amount of the bombardment process gas, e.g., argon, in the process gas mixture. So, reducing of the amount of bombardment process gas in the process gas mixture may serve to reduce the intensity of the plasmoids. However, the higher percentage of bombardment process gas is also typically necessary to provide sufficient plasma density to ensure proper film formation. Also, a large amount of RF power is needed to generate the plasma, because if there is not enough RF power applied, the plasma density will not be sufficient. However, increasing the applied RF power leads to formation of more plasmoids. Some process applications use about 300 W of applied RF power per 300 mm diameter wafer processing station. However, other process applications may require higher RF power, such as 400 W, or even higher, per 300 mm diameter wafer processing station.

In view of the foregoing, one approach for suppressing plasmoid formation is to reduce the applied RF power and/or increase the oxygen concentration within the gas mixture. More specifically, lower process power, i.e., lower applied RF power, or lower bombardment gas (typically argon) concentration within the process gas (with respect to oxygen) results in a lower plasma density, thus suppressing formation of plasmoids. Unfortunately, these conditions are not preferred from a deposited film quality perspective. For example, film quality is degraded when ion bombardment from the plasma is not sufficient at lower process power or lower bombardment gas concentration within the process gas. Therefore, it may not always be possible to maintain deposited film quality while suppressing plasmoid formation through lowering of the process power and/or lowering of the bombardment gas concentration, e.g., argon concentration, within the process gas.

Systems and methods are disclosed herein to prevent/suppress plasma instability by modulating electrical potential of the wafer 101. In some embodiments, a low positive DC bias is applied to the backside/underside of the wafer 101. This low positive DC bias is effective in suppressing the formation of plasmoids. The systems and methods disclosed herein for suppression and/or prevention of plasma instability does not require changes in other process conditions, such as process gas flow rates, pressure, and/or applied RF power.

FIG. 5A shows a vertical cross-section view of the pedestal 140 of FIG. 1A, in accordance with some embodiments of the present invention. In some embodiments, the pedestal 140 is formed of an electrically conductive material, such as aluminum, among other materials. In some embodiments, the pedestal 140 includes heating devices 505, such as electrical resistance heaters. The pedestal 140 includes a top surface 502. The electrical insulating layer 507 is disposed on the top surface 502 of the pedestal 140. The electrical insulating layer 507 is formed of a dielectric material that is compatible with the materials used in the processing of the wafer 101 and that is stable with regard to thermal expansion during processing of the wafer 101. In various embodiments, during processing of the wafer 101, the pedestal 140 can be exposed to temperatures within a range extending up to about 100° Celsius (C), or within a range extending from about 20° C. to about 100° C., or to temperatures within a range extending up to about 50° C., or to temperatures within a range extending up to about 250° C.

In some embodiments, the electrical insulating layer 507 is formed of a ceramic material, such as a ceramic plate or ceramic coating. In some embodiments, the electrical insulating layer 507 is formed by anodizing the top surface 502 of the pedestal 140. In some embodiments, the electrical insulating layer 507 has a vertical thickness as measured in a direction perpendicular to the top surface 502 of the pedestal 140 within a range extending up to about 1 millimeter (mm), or within a range extending up to about 100 micrometers, or within a range extending from about 10 micrometers to about 50 micrometers, or of about 30 micrometers. It should be understood, however, that in other embodiments the vertical thickness of the electrical insulating layer 507 as measured in the direction perpendicular to the top surface 502 of the pedestal 140 can be different than the above-mentioned ranges and values. The vertical thickness of the electrical insulating layer 507 is defined to ensure that electrical current does not flow through the electrical insulating layer 507 to the pedestal 140.

The electrically conductive layer 509 is disposed on the electrically insulating layer 507. The electrically conductive layer 509 is configured to support the wafer 101. In some embodiments, the electrically conductive layer 509 is formed to have a vertical thickness as measured perpendicular to the top surface 502 of the pedestal 140 within a range extending up to about 1 mm, or within a range extending up to about 0.25 inch, or within a range extending up to about 0.5 inch. It should be understood, however, that in other embodiments the vertical thickness of the electrically conductive layer 509 as measured in the direction perpendicular to the top surface 502 of the pedestal 140 can be different than the above-mentioned ranges and values. In some embodiments, the electrically conductive layer 509 is formed as a solid plate. In some embodiments, the electrically conductive layer 509 is formed as a laminated film. In some embodiments, the electrically conductive layer 509 is formed as a sprayed metal coating. In some embodiments, the electrically conductive layer 509 is formed of aluminum. However, it should be understood that in other embodiments the electrically conductive layer 509 can be formed of essentially any type of electrically conductive material that is compatible with the materials used in the processing of the wafer 101 and that is stable with regard to thermal expansion during processing of the wafer 101.

In some embodiments, the electrically conductive layer 509 includes a distribution of MCA's 511 configured to contact and support the wafer 101. In these embodiments, the MCA's 511 are formed of electrically conductive material to provide for transmission of electrical current from the electrically conductive layer 509 to the wafer 101. In some embodiments, the MCA's 511 are formed of a same material as the electrically conductive layer 509. In some embodiments, the MCA's 511 are formed of a different material than the electrically conductive layer 509, so long as the MCA's 511 are formed of an electrically conductive material. In some embodiments, the MCA's 511 are formed integrally with the electrically conductive layer 509. In some embodiments, the MCA's 511 are physically attached to the electrically conductive layer 509. In some embodiments, the MCA's 511 are configured to have a rounded top surface that contacts the backside/underside of the wafer 101. In some embodiments, the MCA's 511 are configured to have a substantially flat top surface that contacts the backside/underside of the wafer 101.

The electrically conductive layer 509 is electrically connected to the DC power supply 521, through an electrical connection 523 that extends through the low pass filter 525. The low pass filter 525 prevents RF signals from entering and damaging the DC power supply 521. A positive terminal of the DC power supply 521 is connected to the electrical connection 523, such that direct electrical current flows through the electrical connection 523, including through the low pass filter 525, to the electrically conductive layer 509, and through the wafer 101 into the plasma within the processing volume overlying the wafer 101. A negative terminal of the DC power supply 521 is connected to an electrical current return structure within the chamber to provide for completion of the circuit. In various embodiments, the electrical connection 523 can be connected to the electrically conductive layer 509 in different ways such as through a soldered connection, a brazed connection, a compression connection, a threaded connection, among others. Electrical conductors that form the electrical connection 523 and/or the contact with the electrically conductive layer 509 are electrically insulated from the pedestal 140 by one or more electrical insulating structures 527. Also, if the pedestal 140 includes heating devices 505, such as electrical resistance heaters, the electrical insulating structures 527 are formed to electrically insulate the heating devices 505 from the electrical connection 523.

Additionally, in some embodiments, at least one of the lift pins within the pedestal 140 is formed of an electrically conductive material, and is configured to electrically contact the electrically conductive layer 509 when retracted to its down position within the pedestal 140, and is electrically connected to the DC power supply 521 through the electrical connection 523 and the low pass filter 525. In these embodiments, the at least one DC powered lift pin can be used to provide electrical connection with the electrically conductive layer 509 in lieu of, or in addition to, forming a permanent contact between the electrically conductive layer 509 and the electrical connection 523.

FIG. 5A also shows the carrier ring 200 which sits in the outer region of the pedestal 140 over a carrier support surface 513. The carrier ring 200 can include a plurality of extensions 515 which secure the carrier ring 200 to prevent the carrier ring 200 from shifting during processing of the wafer 101. The extensions 515 are configured to sit in the carrier ring supports 412 a, 412 b, and 412 c, as shown in FIG. 4A. FIG. 5B shows a close-up view of the region 501 referenced in FIG. 5A, in accordance with some embodiments of the present invention. FIG. 5C also shows a close-up view of the region 501 referenced in FIG. 5A, in accordance with some embodiments of the present invention. In the example embodiment of FIG. 5C, the pedestal 140 includes a retainer structure 142 configured to extend upward from the top surface 502 of the pedestal 140, and configured to circumscribe the region within which the electrical insulating layer 507 and the electrically conductive layer 509 are formed. Also, in the example embodiment of FIG. 5C the electrical insulating layer 507 is formed to extend upward along an inner surface of the retainer structure 142 to provide for electrical insulation between the retainer structure 142 and the electrically conductive layer 509.

FIG. 5D also shows a close-up view of the region 503 referenced in FIG. 5A, in accordance with some embodiments of the present invention. In the example embodiment of FIG. 5D, an electrical connection 512 is shown as formed between the electrically conductive layer 509 and the electrical connection 523. In various embodiments, the electrical connection 523 can be a soldered connection, a brazed connection, a compression connection, a threaded connection, among others. FIG. 5E also shows a close-up view of the region 503 referenced in FIG. 5A, in accordance with some embodiments of the present invention. In the example embodiment of FIG. 5E, the electrical connection 512 is formed as a wider, pad-type structure between the electrically conductive layer 509 and the electrical connection 523. In the example embodiment of FIG. 5E, the electrical insulating layer 507 is formed to wrap around the electrical connection 523.

During operation, the DC power supply 521 can be operated to cause a flow of DC electrical current from the DC power supply 521 through the electrical connection 523, including through the low pass filter 525, to the electrically conductive layer 509, through the MCA's 511 supporting the wafer 101, through the wafer 101, to the plasma overlying the wafer 101, and through the plasma to an electrically conductive return structure in contact with the plasma. Positive electrical charges near the wafer 101 caused by the DC electrical current serve to repel positively charged ions within the plasma overlying the wafer 101, which serves to suppress formation of plasmoids at the wafer 101 surface. In some embodiments, the DC electrical current transmitted from the DC power supply 521 is within a range extending up to 100 milliAmperes (mA), or within a range extending from about 30 mA to about 70 mA. It should be understood, however, that in some embodiments the DC electrical current transmitted from the DC power supply 521 can be different than the above-mentioned ranges and values. In some embodiments, a voltage applied by the DC power supply 521 to the electrical connection 523 is within a range extending up to about +30 volts (V), or within a range extending from about −10 V to about +50 V, or within a range extending from about +20 V to about +40 V, or within a range extending from about +10 V to about +30 V. It should be understood, however, that in some embodiments the voltage applied by the DC power supply 521 can be different than the above-mentioned ranges and values.

Because the DC electrical current supplied from the DC power supply 521 flows to the wafer 101 through the MCA's 511, the spatial arrangement of the MCA's 511 may have an effect on the spatial distribution of the DC electrical current flow from the wafer 101 to the plasma, and in turn have a spatial effect on the suppression of plasmoid formation across the wafer 101. FIG. 5F shows a top view of the electrically conductive layer 509 corresponding to referenced view A-A as identified in FIG. 5A, in accordance with some embodiments of the present invention. In the example embodiment of FIG. 5F, the MCA's 511 (corresponding to the small circles denoted by 511 (typ.)) are distributed in a substantially uniform manner across the electrically conductive layer 509 so as to contact the backside/underside of the wafer 101 with a substantially uniform spatial arrangement. The spatial arrangement of the MCA's 511 can be used to increase/decrease electrical conductance to the wafer 101 in different spatial areas, and thereby provide for spatial control of the plasmoid suppression. For example, in some embodiments, more MCA's 511 can be provided at locations where higher plasmoid formation is expected, so as to provide for increase flow of DC electrical current through the wafer 101 at those locations.

FIG. 5G shows a top view of the electrically conductive layer 509 corresponding to referenced view A-A as identified in FIG. 5A, in accordance with some embodiments of the present invention. In the example embodiment of FIG. 5G, a spatial density of the MCA's 511 is increased toward an outer radial periphery of the electrically conductive layer 509. Therefore, the spatial arrangement of the MCA's 511 in the example embodiment of FIG. 5G may be used in processing applications where increased plasmoid formation is expected near the outer radial region of the wafer 101. It should be understood that the MCA 511 spatial arrangements depicted in the example embodiments of FIGS. 5F and 5G are provided for purposes of description and do not represent all possible spatial arrangements of the MCA's 511 across the electrically conductive layer 509. In other embodiments, the MCA's 511 can have essentially any spatial arrangement that provides for adequate structural support of the wafer 101 and that provides for a suitable distribution of DC electrical current flow from the electrically conductive layer 509 to the wafer 101.

FIG. 6 shows a schematic of DC electrical current flow from the DC power supply 521 through the chamber 102, in accordance with some embodiments of the present invention. FIG. 6 shows the showerhead electrode 150/150A connected to receive RF signals from the RF power supply 104 by way of the match network 106 to generate a plasma 601 within the region overlying the wafer 101. In the example embodiment of FIG. 6, the showerhead electrode 150/150A is connected to the return (negative terminal) of the DC power supply 521, as indicated by electrical connections 605, where the return (negative terminal) of the DC power supply 521 is electrically connected to a reference ground potential. In this manner, the DC electrical current (i) flows from the DC power supply 521, through the low pass filter 525, to the electrically conductive layer 509, as indicated by electrical connection 523, and through the MCA's 511 to the wafer 101, and through the wafer 101 to the plasma 601, and through the plasma 601 to the showerhead electrode 150/150A, and from the showerhead electrode 150/150A through electrical connection 605 to the return (negative terminal) of the DC power supply 521.

FIG. 7 shows an alternate schematic of DC electrical current flow from the DC power supply 521 through the chamber 102, in accordance with some embodiments of the present invention. The example embodiment of FIG. 7 corresponds to a low pressure processing application in which the plasma 601 contacts the wall of the chamber 102. In the example embodiment of FIG. 7, the wall of the chamber 102 functions as a return electrode for the DC electrical current (i) that flows from the DC power supply 521. More specifically, the wall of the chamber 102 is electrically connected to the return (negative terminal) of the DC power supply 521 through an electrical connection 701. During operation, the DC electrical current (i) flows from the DC power supply 521, through the low pass filter 525, to the electrically conductive layer 509, as indicated by electrical connection 523, and through the MCA's 511 to the wafer 101, and through the wafer 101 to the plasma 601, and through the plasma 601 to the wall of the chamber 102, and from the wall of the chamber 102 through the electrical connection 701 to the return (negative terminal) of the DC power supply 521.

As discussed above, in various wafer 101 processing applications, the wafer 101 is loaded onto a processing station, such as a deposition station, and is placed on the electrically conductive layer 509 of the pedestal 140/140A. The wafer 101 is supported by a set of conductive pins/structures, such as the MCA's 511, that are electrically connected to the electrically conductive layer 509. Then, DC voltage is applied from the external DC power supply 521 to the wafer 101 through the electrically conductive layer 509 and through the conductive pins/structures, e.g., through the MCA's 511. The applied DC voltage is used to reduce the energy flux of (positive) ions within the plasma that are incident upon the wafer 101. Energetic ions from the plasma may eject secondary electrons from the film material deposited on the wafer 101. These secondary electrons can be accelerated to high energy when pulled into the bulk plasma through the plasma sheath. These accelerated electrons may form regions of high-density, unstable plasma, such as the plasmoids. Such a behavior is observed in argon-rich gas mixtures when discharge interacts with specific surfaces (e.g., film of specific composition and thickness). In order to shift wafer potential, the applied DC voltage generates a non-zero flow of DC electrical current. Without the non-zero flow of DC electrical current, application of the external DC voltage may be ineffective due to an ability of the plasma to shadow wafer 101 surface charge with charges of opposite sign, thereby restoring a floating potential of the wafer 101.

It should be appreciated that the system and methods disclosed herein for suppressing plasma instabilities, such as plasmoids, adds a minimum perturbation to the processing system. The DC bias applied to the backside/underside of a wafer 101 serves as a process tuning parameter which may be adjusted to eliminate plasmoids while having minimal impact on the discharge and the process. Flow rate, pressure, RF power, and other parameters can remain the same with application of the DC bias to the backside/underside of the wafer 101.

Application of DC bias to the wafer backside/underside of the wafer 101 is not common. In some situations, DC bias may be applied to the RF powered electrode, e.g., to the showerhead electrode 150/150A, to modulate global plasma structure. However, application of DC bias to the showerhead electrode 150/150A does not suppress plasmoids because DC current primarily flows between showerhead electrode 150/150A and the wall of the chamber 102, with minimum effect on the plasma-to-wafer interface. In contrast to applying DC bias to the showerhead electrode 150/150A, the systems and methods disclosed herein establish a DC electrical connection with the backside/underside of the wafer 101. And, in some embodiments, this DC electrical connection to the backside/underside of the wafer 101 is established by multiple conductive wafer support structures, e.g., MCA's 511, distributed spatially across the backside/underside of the wafer 101. These multiple conductive wafer support structures create low electrical resistance contact with the wafer 101 and conduct DC current to the wafer 101 so as to modify the electric potential of the wafer 101. Generally speaking, various methods for increasing the electric potential of the wafer 101 may serve to reduce the likelihood of plasmoid formation. In an alternate embodiment, even DC grounding of the wafer 101 may serve to reduce some plasma instability, as opposed to having the wafer 101 be at a floating electric potential. Such an alternate embodiment may be considered a special case of DC biasing with zero voltage.

In view of the foregoing, it should be understood that an apparatus for supporting a wafer during a plasma processing operation is disclosed herein. The apparatus includes the pedestal 140/140A configured to have bottom surface and a top surface. The apparatus also includes the column 141 configured to support the pedestal 140/140A at a central region of the bottom surface of the pedestal 140/140A. In some embodiments, the column 141 is configured to rotate. And, in these embodiments, the column 141 is fixed to the pedestal 140/140A such that rotation of the column 141 causes corresponding rotation of the pedestal 140/140A. The apparatus includes an electrical insulating layer 507 disposed over the top surface of the pedestal 140/140A. In some embodiments, the electrical insulating layer 507 is formed integrally with the pedestal, such as shown in FIG. 1B. The apparatus also includes an electrically conductive layer 509 disposed over the top surface of the electrical insulating layer 507. The apparatus also includes at least three support structures 511 distributed on the electrically conductive layer 509. Each of the at least three support structures 511 is formed of electrically conductive material and is secured in electrical contact with the electrically conductive layer 509. The at least three support structures 511 are configured to interface with a bottom surface of a wafer 101 to physically support the wafer 101 and electrically connect to the wafer 101. The apparatus also includes an electrical connection 523 extending from the electrically conductive layer 509 to a location outside of the pedestal 140/140A. The electrical connection 523 is electrically connected to the positive terminal of the direct current power supply 521.

In some embodiments, the electrical insulating layer 507 has a vertical thickness as measured in a direction perpendicular to the top surface of the pedestal 140/140A at least large enough to prevent flow of electrical current from the electrically conductive layer 509 to an electrically conductive material located within the pedestal 140/140A below the electrical insulating layer 507. In some embodiments, the electrical insulating layer 507 has a vertical thickness as measured in a direction perpendicular to the top surface of the pedestal 140/140A within a range extending up to about 1000 micrometers, or within a range extending up to about 100 micrometers, or within a range extending from about 10 micrometers to about 50 micrometers, or of about 30 micrometers. It should be understood, however, that in other embodiments the vertical thickness of the electrical insulating layer 507 as measured in the direction perpendicular to the top surface of the pedestal 140/140A can be different than the above-mentioned ranges and values. In some embodiments, the electrically conductive layer 509 has a vertical thickness as measured in a direction perpendicular to the top surface of the pedestal 140/140A within a range extending up to about 1 millimeter, or within a range extending up to about 7 millimeters, or within a range extending up to about 13 millimeters. It should be understood, however, that in other embodiments the vertical thickness of the electrically conductive layer 509 as measured in the direction perpendicular to the top surface of the pedestal 140/140A can be different than the above-mentioned ranges and values. In various embodiments, the electrically conductive layer 509 is formed as either a plate, or a laminated film, or a sprayed coating.

In some embodiments, the at least three support structures 511 are distributed in a substantially uniform manner across the electrically conductive layer 509, such as shown in FIG. 5F, by way of example. In some embodiments, the at least three support structures 511 are distributed in a non-uniform manner across the electrically conductive layer 509, such as shown in FIG. 5G, by way of example. In some embodiments, a larger number of the at least three support structures 511 are positioned near a peripheral region of the electrically conductive layer 509 as compared to near a central region of the electrically conductive layer 509.

In some embodiments, both the at least three support structures 511 and the electrically conductive layer 509 are formed of a same material. And, in some embodiments, the electrically conductive layer 509 is formed of a material different than a material of which the at least three support structures 511 are formed, with the at least three support structures 511 formed of an electrically conductive material. In some embodiments, both the at least three support structures 511 and the electrically conductive layer 509 are formed as a single integral structure. In some embodiments, the at least three support structures 511 are attached to the electrically conductive layer 509. Also, in some embodiments, each of the at least three support structures 511 is configured to have a rounded top surface for interfacing with the bottom surface of the wafer 101.

Also, in view of the foregoing, it should be understood that a system for plasma processing of a wafer is disclosed herein. The system includes the direct current power supply 521 that has the positive terminal and the negative terminal. The system also includes a low pass filter circuit, e.g., low pass filter 525, that has an input connection and an output connection, with the input connection of the low pass filter circuit 525 electrically connected to the positive terminal of the direct current power supply 521. The system also includes a wafer support apparatus that includes at least three support structures 511 distributed to physically contact and support a bottom surface of the wafer 101. Each of the at least three support structures 511 is formed of electrically conductive material. And, each of the at least three support structures 511 is electrically connected to the output connection of the low pass filter circuit 525.

In some embodiments, the wafer support apparatus includes the electrically conductive layer 509, with the at least three support structures 511 physically and electrically connected to the electrically conductive layer 509, and with the electrically conductive layer 509 being electrically connected to the output connection of the low pass filter circuit 525. Also, in some embodiments, the wafer support apparatus includes the pedestal 140/140A configured to have a bottom surface and a top surface. And, the wafer support apparatus includes the electrical insulating layer 507 disposed below the electrically conductive layer 509. And, in some embodiments, the wafer support apparatus includes the column 141 configured to support the pedestal 140/140A at a central region of the bottom surface of the pedestal 140/140A. In some embodiments, the column 141 is configured to rotate, with the column 141 fixed to the pedestal 140/140A such that rotation of the column 141 causes corresponding rotation of the pedestal 140/140A.

The system also includes an electrode, such as the showerhead electrode 150/150A, by way of example, positioned above the wafer support apparatus. A plasma generation region is located between the electrode 150/150A and the wafer support apparatus. The system also includes the radiofrequency power supply 104 connected to deliver radiofrequency power to the electrode 150/150A. The system also has the negative terminal of the direct current power supply 521 electrically connected to at least one electrically conductive structure exposed to the plasma generation region. In some embodiments, such as shown in FIG. 6, the at least one electrically conductive structure exposed to the plasma generation region is the electrode 150/150A. In some embodiments, such as shown in FIG. 7, the at least one electrically conductive structure exposed to the plasma generation region is a wall of the chamber 102 in which the electrode 150/150A and the wafer support apparatus are disposed.

FIG. 8 shows a flowchart of a method for plasma processing of a wafer, in accordance with some embodiments of the present invention. The method includes an operation 801 for positioning a wafer (101) on at least three support structures (511) distributed to physically contact and support a bottom surface of the wafer (101). Each of the at least three support structures (511) is formed of electrically conductive material. Also, each of the at least three support structures (511) is electrically connected to a positive terminal of a direct current power supply (521).

The method also includes an operation 803 for providing an electrical current return path from a plasma generation region overlying the wafer (101) to a negative terminal of the direct current power supply (521). In some embodiments, such as shown in FIG. 6, by way of example, the electrical current return path is provided from the plasma generation region through an electrode (such as the showerhead electrode 150/150A), and from the electrode (150/150A) to the negative terminal of the direct current power supply (521). In some embodiments, such as shown in FIG. 7, by way of example, the electrical current return path is provided from the plasma generation region through a wall of a chamber (102) within which the plasma generation region is formed, and from the wall of the chamber (102) to the negative terminal of the direct current power supply (521).

The method also includes an operation 805 for generating a plasma (601) within the plasma generation region overlying the wafer (101). In some embodiments, generating the plasma (601) within the plasma generation region in operation 805 includes supplying radiofrequency power to an electrode (such as showerhead electrode 150/150A) overlying the plasma generation region. The method also includes an operation 807 for operating the direct current power supply (521) to drive an electrical current through the at least three support structures (511), and from the at least three support structures (511) through the wafer (101), and from the wafer (101) through the plasma (601), and from the plasma (601) through the electrical current return path to the negative terminal of the direct current power supply (521). Driving of the electrical current in operation 807 is performed in conjunction with generating the plasma (601) in operation 805.

In some embodiments, operation 807 includes operating the direct current power supply (521) to generate an electrical current within a range extending up to about 100 milliAmperes, or within a range extending from about 30 milliAmperes to about 70 milliAmperes. It should be understood, however, that in some embodiments the DC electrical current transmitted from the DC power supply 521 can be different than the above-mentioned ranges and values. In some embodiments, operation 807 includes operating the direct current power supply (521) to generate an electrical voltage within a range extending up to about +30 volts, or within a range extending from about −10 volts to about +50 volts, or within a range extending from about +20 volts to about +40 volts, or within a range extending from about +10 volts to about +30 volts. It should be understood, however, that in some embodiments the voltage applied by the DC power supply 521 can be different than the above-mentioned ranges and values.

Argon-rich plasma is often unstable and shows different types of instability at a pressure of about 1 Torr to a few Torr and with a vertical separation between the pedestal 140/140A and the showerhead electrode 150/150A of about 0.3 inch to about 0.5 inch, which are pressure and vertical separation conditions that may be present in many plasma processing applications. As previously discussed, the plasmoid is a form of plasma instability that may be encountered in such plasma processing applications. The plasmoid is a local high-density plasma that is initiated and sustained by high energy electrons. When the plasmoid occurs, the deposited film is locally densified and film thickness uniformity is correspondingly degraded. It is difficult to predict exactly when and where plasmoid formation will occur due to the nature of the plasmoid instability.

Plasmoid occurrence can be identified by measuring the thickness profile of the deposited film on an individual wafer after completion of the film deposition process. When the plasmoid is formed, the film on the wafer is exposed to high-energy ion bombardment, which thins the film. The measured thickness profile of the deposited film shows local thin spots that are caused by the plasmoid. In general, it is not practical to measure the film thickness profile of all wafers to determine whether or not the film was exposed to plasmoid degradation/thinning and to verify that the deposited film has not been degraded. Moreover, it is not practical to use human visual observation to detect the occurrence of plasmoids during plasma processing of all wafers. Therefore, it is of interest to develop improved methods by which plasmoids can be detected during plasma processing operations.

Methods are also disclosed herein for detecting plasma instabilities, such as plasmoid formation, by analyzing optical emissions from the plasma to identify a presence of an optical signature that is indicative of plasmoid formation within the plasma. In some embodiments, the optical emission from the plasma is monitored and analyzed to identify formation of plasmoids during plasma processing. The monitoring and analysis of the optical emission from the plasma includes: 1) determining an intensity of optical emission corresponding to excited neutral atoms of the process gas at a wavelength of optical emission of the excited neutral atoms of the process gas, such as at a wavelength of about 750 nanometers (nm) for argon process gas, and 2) determining an intensity of optical emission corresponding to excited ions of the process gas at a wavelength of optical emission of the excited ions of the process gas, such as at a wavelength of about 480 nm for argon process gas, and 3) determining a ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas, and 4) evaluating the calculated ratio to determine whether or not a plasmoid has occurred.

FIG. 9 shows an example optical emission spectra of an argon/oxygen plasma, in accordance with some embodiments of the present invention. The plasma corresponding to FIG. 9 is generated using a process gas composition of argon at 10,000 sccm (standard cubic centimeters per minute) and oxygen at 500 sccm, at a pressure of about 1.5 Torr, and with application of continuous wave RF power at a frequency of 13.56 MHz (megaHertz). As shown in FIG. 9, the optical emission corresponding to excited argon ions corresponds to a photon wavelength within a range extending from about 400 nm to about 500 nm, and the optical emission corresponding to excited neutral argon atoms corresponds to an photon wavelength within a range extending from about 700 nm to about 800 nm.

When a plasmoid occurs, the optical emission from excited neutral atoms of the process gas remains substantially unchanged. However, when a plasmoid occurs, the optical emission from excited ions of the process gas increases. Therefore, the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas can be used to determine whether or not plasmoid formation has occurred. More specifically, a significant increase in the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas indicates that plasmoid formation has occurred.

In some embodiments, a factor of at least 3 increase in the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas indicates that plasmoid formation has occurred. In some embodiments, a factor of at least 5 increase in the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas indicates that plasmoid formation has occurred. In some embodiments, a factor of at least 7 increase in the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas indicates that plasmoid formation has occurred. In some embodiments, a factor of at least 9 increase in the ratio of the intensity of optical emission of the excited ions of the process gas to the intensity of optical emission of the excited neutral atoms of the process gas indicates that plasmoid formation has occurred.

FIG. 10 shows a plot of the ratio of intensity of optical emission observed with and without plasmoid formation, in accordance with some embodiments of the present invention. In FIG. 10, the Ar (argon) I optical emission lines (750 nm and 764 nm wavelength) represent the ratio of intensity of optical emission corresponding to excited neutral argon atoms with plasmoids present relative to without plasmoids present. The ratio of intensity for the excited neutral argon atoms is about 1 at both Ar I emission lines of 750 nm and 764 nm wavelength. Therefore, the intensity of optical emission corresponding to excited neutral argon atoms remains about the same with and without plasmoids present. However, as shown in FIG. 10, the Ar II optical emission lines (477 nm and 481 nm wavelength) corresponding to excited argon ions indicate a dramatic change with plasmoids present as compared to without plasmoids present. Specifically, the ratio of intensity of optical emission corresponding to excited argon ions with plasmoids present relative to without plasmoids present is greater than 7. Therefore, the presence of plasmoids causes the optical emission intensity of excited argon ions to increase by a factor of more than 7. Therefore, plasmoid formation is sustained by high energy electrons, such as secondary electrons emitted from the oxide film.

FIG. 11 shows a plot of normalized optical emission intensity as a function of applied RF power, in accordance with some embodiments of the present invention. FIG. 11 shows that when plasmoid formation occurs at an applied RF power between 1600 W and 1800 W, the intensity of optical emission from excited argon ions increased by about a factor of 10, while the intensity of optical emission from excited neutral argon atoms remains about the same. Therefore, the ratio of the intensity of optical emission of the excited argon ions relative to the intensity of optical emission of the excited neutral argon atoms can be used as an optical signature to detect formation of plasmoids within the plasma.

In various embodiments, different types of optical emission collection devices can be used to collect optical emissions from the plasma for analysis. FIG. 12 shows the wafer processing system 100/100A having various optical emission collection devices configured to collect optical emission data from the plasma 601 for processing by an optical signal processing unit 1201, in accordance with some embodiments of the present invention. In some embodiments, the wafer processing system 100/100A can include the DC power supply 521, low pass filter 525, and electrical connection 523 as previously described with regard to FIGS. 6 and 7.

In some embodiments, the optical emission collection devices include optical fibers embedded within the chamber 102 to provide for collection of optical emissions from the plasma 601. These optical fibers are connected to a spectrometer within the optical signal processing unit 1201 to analyze and monitor the optical emission lines corresponding to the excited ions of the process gas and the excited neutral atoms of the process gas. For example, in some embodiments, optical fibers 1213 are mounted on the carrier ring 200, such that light input ends of the optical fibers 1213 are exposed to the plasma 601. Also, in some embodiments, optical fibers 1211 are embedded within the chamber 102 wall at one or more positions that provide for collection of optical emissions from the plasma 601 by the optical fibers 1211. Also, in some embodiments, optical fibers 1209 are installed on/through the backside of the showerhead electrode 150A to provide for collection of optical emissions from the plasma 601 by the optical fibers 1209 and to minimize deposition on the optical fibers 1209. Also, in some embodiments, any of optical fibers 1209, 1211, and 1213 can be combined with a lens system to enable positioning of the optical fibers to view the optical emission from the plasma through a viewport 1203 of the chamber 102. These embodiments allow the optical fibers to be maintained in atmospheric conditions outside of the processing chamber 102.

It should be understood that in various embodiments, the optical fibers 1209, 1211, and 1213 depicted in FIG. 12 can be implemented either alone or in any combination with each other. It should also be understood that the optical fibers 1209, 1211, and 1213 depicted in FIG. 12 are shown by way of example, and do not represent all possible configurations and placements of optical fibers to view optical emissions from the plasma 601. In some embodiments, optical fibers and corresponding placements different than those of optical fibers 1209, 1211, and 1213 can be implemented, so long as the optical fibers are positioned to view optical emissions from the plasma 601, and are routed to the optical signal processing unit 1201, and are configured to not interfere with plasma processing operations within the chamber 102.

Additionally, in some embodiments, one or more optical collection devices 1205 can be installed on the viewport 1203 of the chamber 102 to view optical emissions from the plasma 601, and possibly process the optical emissions from the plasma 601, and transmit optical emission data and/or signals to the optical signal processing unit 1201 through a connection 1207. For example, in some embodiments, the optical collection device 1205 can be defined as a charge coupled device (CCD) camera with bandpass filters configured to selectively measure the optical emission lines corresponding to the excited ions of the process gas and the excited neutral atoms of the process gas. The CCD cameras can be installed on the viewport 1203 of the chamber 102 and can be equipped with lenses as needed to collect the optical emissions from the plasma 601. Also, in some embodiments, the optical collection device 1205 can include one or more photodiodes configured to collect the optical emissions from the plasma 601.

In some embodiments, the optical signal processing unit 1201 can be used to analyze the collected plasma optical emission data off-line, i.e., separate from the actual plasma processing of the wafer. And, in some embodiments, the optical signal processing unit 1201 can be used to analyze the collected plasma optical emission data on-line and in real-time. In such embodiments, real-time detection of plasmoid formation is possible through use of the optical signal processing unit 1201. With real-time detection of plasmoid formation provided by way of the optical signal processing unit 1201, a feedback loop can be established between the optical signal processing unit 1201 and the RF power supply 104, as indicated by connection 1106, to provide for tuning of the plasma process to suppress plasmoid formation in real-time. In some embodiments, tuning of the plasma process to suppress plasmoid formation can include modification of characteristics of the applied RF power. The above-mentioned feedback loop can provide for real-time suppression of plasmoid formation. More specifically, because plasmoid formation can be suppressed by lowering the RF power applied to generate and sustain the plasma 601, or by changing another RF generation parameter, such as RF frequency, detection of plasmoid formation through collection and analysis of optical emissions from the plasma 601 using the optical signal processing unit 1201 can be used to trigger the RF power supply 104 to lower its output RF power, or change another RF generation parameter, until the plasmoid is no longer detected.

Also, in some embodiments, the optical signal processing unit 1201 is configured and connected to transmit control signals to the DC power supply 521, as indicated by connection 1108, to provide for tuning of the plasma process to suppress plasmoid formation in real-time by either directing an increase or a decrease in the DC power supplied to the wafer 101. As discussed herein, the DC bias applied to the backside/underside of the wafer 101 by the DC power supply 521, through the electrical connection 523 and the electrically conductive layer 509, serves as a process tuning parameter which may be adjusted to eliminate plasmoids while having minimal impact on the discharge and the process.

Given the foregoing, it should be understood that a system is disclosed herein for plasma processing of a wafer, such as the wafer processing system 100/100A of FIG. 12. The system 100/100A includes the wafer support apparatus 140/140A configured to support the wafer 101 during a plasma processing operation. The system 100/100A also includes the electrode 150/150A positioned above the wafer support apparatus 140/140A so as to form a plasma generation region between the electrode 150/150A and the wafer support apparatus 140/140A. The system 100/100A also includes the radiofrequency power supply 104 connected to deliver radiofrequency power to the electrode 150/150A. The system 100/100A also includes at least one optical emission collection device, such as optical fibers 1209, 1211, and 1213 and/or optical collection device 1205, disposed to collect optical emissions from the plasma 601 to be generated within the plasma generation region. The system also includes the optical signal processing unit 1201 configured to analyze optical emissions collected by the at least one optical emission collection device to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions. The optical signal processing unit 1201 is configured to provide notification of determining that the optical signature of the plasma instability does exist in the collected optical emissions.

The system also includes a process gas supply 1215 configured to supply a process gas to the plasma generation region, as indicated by the connection 1217 to the showerhead electrode 150/150A. In some embodiments, the process gas is distributed to the plasma generation region by the showerhead electrode 150/150A. In some embodiments, the optical signal processing unit 1201 is configured to determine an intensity of optical emission corresponding to excited neutral atoms of the process gas when the process gas is excited by radiofrequency power emanating from the electrode 150/150A to generate the plasma 601 within the plasma generation region. And, the optical signal processing unit 1201 is configured to determine an intensity of optical emission corresponding to excited ions of the process gas. And, the optical signal processing unit 1201 is configured to determine an indicator ratio of the intensity of optical emission corresponding to excited ions of the process gas to the intensity of optical emission corresponding to excited neutral atoms of the process gas. And, the optical signal processing unit 1201 is configured to determine whether or not the indicator ratio has increased by a threshold amount so as to indicate that the plasma instability does exist in the collected optical emissions. In various embodiments, the threshold amount is at least 3, or at least 5, or at least 7, or at least 9, or at least 10.

In some embodiments, the process gas includes argon. And, with the process gas including argon, the optical signal processing unit 1201 is configured to determine the intensity of optical emission corresponding to excited neutral atoms of the argon process gas at a wavelength of about 750 nanometers. And, with the process gas including argon, the optical signal processing unit 1201 is configured to determine the intensity of optical emission corresponding to excited ions of the argon process gas at a wavelength of about 480 nanometers. However, it should be understood that in other embodiments, the process gas composition can include an optical emitting gas other than argon, such as helium, among others, where the optical emitting gas is the material having its optical emissions measured at its corresponding optical emission wavelengths for excited neutral atoms and excited ions.

In some embodiments, the system 100/100A can also include the feedback connection 1106 between the optical signal processing unit 1201 and the radiofrequency power supply 104. The optical signal processing unit 1201 is configured to generate and transmit control signals through the feedback connection 1106 to control the radiofrequency power supply 104 based on the determination of whether or not an optical signature indicative of plasma instability, e.g., plasmoid formation, exists in the collected and analyzed optical emissions from the plasma 601.

Also, in some embodiments, the system 100/100A can include the direct current power supply 521 electrically connected to supply electrical current to the wafer support apparatus 140/140A and directly to an underside of the wafer 101 to be supported on the wafer support apparatus 140/140A during the plasma processing operation. Additionally, in some of these embodiments, the system 100/100A can include the feedback connection 1108 between the optical signal processing unit 1201 and the direct current power supply 521. In these embodiments, the optical signal processing unit 1201 is configured to generate and transmit control signals through the feedback connection 1108 to control the direct current power supply 521 based on the determination of whether or not an optical signature indicative of plasma instability, e.g., plasmoid formation, exists in the collected and analyzed optical emissions from the plasma 601. It should also be understood that in some embodiments, the system 100/100A includes both the feedback connection 1108 between the optical signal processing unit 1201 and the direct current power supply 521 and the feedback connection 1106 between the optical signal processing unit 1201 and the radiofrequency power supply 104, as discussed above.

FIG. 13 shows a flowchart of a method for plasma processing of a wafer, in accordance with some embodiments of the present invention. It should be understood that the method of FIG. 13 can be implemented using the wafer processing system 100/100A of FIG. 12. The method includes an operation 1301 for positioning a wafer (101) on a wafer support apparatus (140/140A). The wafer support apparatus (140/140A) is positioned beneath an electrode (150/150A) such that a plasma generation region exists between the wafer (101) and the electrode (150/150A). The method also includes an operation 1303 for supplying radiofrequency power to the electrode (150/150A) to generate a plasma (601) within the plasma generation region. The method also includes an operation 1305 for collecting optical emissions from the plasma (601) using one or more optical emission collection devices. The method also includes an operation 1307 for analyzing the collected optical emissions to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions. The method also includes an operation 1309 for adjusting at least one plasma generation parameter to mitigate formation of the plasma instability, upon determining that the optical signature of the plasma instability does exist in the collected optical emissions. In some embodiments, the plasma instability is a plasmoid characterized by an area of higher density plasma surrounded by larger volumes of normal density plasma. In some embodiments, the optical signature of the plasma instability exhibits an increase in a ratio of a number of excited ions of a process gas to a number of excited neutral atoms of the process gas.

In some embodiments, the method includes supplying a process gas composition to the plasma generation region. The process gas composition is excited by radiofrequency power emanating from the electrode (150/150A) to generate the plasma (601) within the plasma generation region. In some embodiments, the method includes controlling a pressure within the plasma generation region within a range extending from about 1 Torr to about 3 Torr. However, it should be understood that in other embodiments the pressure within the plasma generation region can controlled within a range less than 1 Torr or within a range greater than 3 Torr. In some embodiments, the method includes controlling a distance as measured perpendicularly between the wafer support apparatus (140/140A) and the electrode (150/150A) to be within a range extending from about 0.3 inch to about 0.5 inch. However, it should be understood that in other embodiments the distance as measured perpendicularly between the wafer support apparatus (140/140A) and the electrode (150/150A) is controlled within a range less than 0.3 inch or within a range greater than 0.5 inch.

In some embodiments, analyzing the collected optical emissions includes: 1) determining an intensity of optical emission corresponding to excited neutral atoms of a process gas, where the process gas is excited by radiofrequency power emanating from the electrode (150/150A) to generate the plasma (601) within the plasma generation region, and 2) determining an intensity of optical emission corresponding to excited ions of the process gas, and 3) determining an indicator ratio of the intensity of optical emission corresponding to excited ions of the process gas to the intensity of optical emission corresponding to excited neutral atoms of the process gas, and 4) determining whether or not the indicator ratio has increased by a threshold amount so as to indicate that the plasma instability does exist in the collected optical emissions. In various embodiments, the threshold amount is at least 3, or at least 5, or at least 7, or at least 9, or at least 10. In some embodiments, the process gas includes argon. And, with the process gas including argon, the intensity of optical emission corresponding to excited neutral atoms of the process gas is determined at a wavelength of about 750 nanometers, and the intensity of optical emission corresponding to excited ions of the process gas is determined at a wavelength of about 480 nanometers. However, it should be understood that in other embodiments, the process gas composition can include an optical emitting gas other than argon, such as helium, among others, where the optical emitting gas is the material having its optical emissions measured at its corresponding optical emission wavelengths for excited neutral atoms and excited ions.

In some embodiments, analyzing the collected optical emissions to determine whether or not the optical signature of the plasma instability exists in the collected optical emissions is done following completion of the plasma processing of the wafer in which the optical emissions were collected. However, in some embodiments, analyzing the collected optical emissions to determine whether or not the optical signature of the plasma instability exists in the collected optical emissions is done in real-time during the plasma processing of the wafer in which the optical emissions were collected. In some embodiments, upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, an amount of radiofrequency power supplied to the electrode is reduced. In some embodiments, upon determining that the optical signature of the plasma instability does not exist in the collected optical emissions, an amount of radiofrequency power supplied to the electrode is increased.

In some embodiments, the method includes operating the direct current power supply (521) to supply electrical current to the wafer support apparatus (140/140A) and from the wafer support apparatus (140/140A) directly to an underside of the wafer (101) during plasma processing of the wafer (101). In these embodiments, upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, an amount of the electrical current supplied by the direct current power supply (521) to the wafer support apparatus (140/140A) is increased to mitigate formation of the plasma instability during plasma processing of the wafer (101).

It is of interest to detect plasmoid formation without measuring on-wafer film thickness. It should be appreciated that the systems and methods disclosed herein provide for detecting plasmoid formation in real-time using optical diagnostic techniques, and without having to measure on-wafer film thickness. It should also be appreciated that the systems and methods disclosed herein for observing and analyzing optical emissions from the plasma to detect formation of plasmoids is non-invasive, is inert to RF signals, and is transparent to the plasma processing of the wafer. And, the systems and methods disclosed herein for observing and analyzing optical emissions from the plasma to detect formation of plasmoids enables identification of when a plasmoid forms and identification of the particular wafer on which the plasmoid forms. Also, the optical analysis provided by the systems and methods disclosed herein enables prevention of formation of plasmoids in real-time. Because plasmoid formation can be suppressed by lowering the RF power applied to generate and sustain the plasma, detection of plasmoid formation through use of the optical sensors (optical fibers, optical collection device(s)) and the optical processing unit can be used to trigger the RF power supply to lower its output RF power, or change some other RF generation parameter, until the plasmoid is no longer detected.

The systems and methods disclosed herein for observing and analyzing optical emissions from the plasma to detect formation of plasmoids saves significant cost and time. For instance, without the systems and methods disclosed herein, the on-wafer thickness profile of the deposited film has to be measured and monitored for each wafer to detect whether or not plasmoid formation occurred during plasma processing of the wafer and whether or not the plasmoids adversely affected the film thickness profile on the wafer. At a fabrication facility where thousands of wafers are processed on a daily basis, measurement of the on-wafer thickness profile of the deposited film is limited to a statistical sampling and is unable to identify each and every individual wafer that was exposed to plasmoids during plasma processing. In contrast, the systems and methods disclosed herein provide for continuous monitoring of the optical emission spectrum from the plasma during plasma processing of each wafer, e.g., during all ALD cycles of all processed wafers. Also, the systems and methods disclosed herein yield directly measured results as they are based on physics, rather than based on statistical correlation that is constrained to specific process conditions. Therefore, the systems and methods disclosed herein provide a general solution for detecting plasmoid formation that can be applied to a wide range of process conditions.

Although the foregoing invention has been described in some detail for purposes of clarity of understanding, it will be apparent that certain changes and modifications can be practiced within the scope of the appended claims. Accordingly, the present embodiments are to be considered as illustrative and not restrictive, and the invention is not to be limited to the details given herein, but may be modified within the scope and equivalents of the described embodiments. 

What is claimed is:
 1. A method for plasma processing of a wafer, comprising: positioning a wafer on a wafer support apparatus, the wafer support apparatus positioned beneath an electrode such that a plasma generation region exists between the wafer and the electrode; supplying radiofrequency power to the electrode to generate a plasma within the plasma generation region; collecting optical emissions from the plasma using one or more optical emission collection devices; analyzing the collected optical emissions to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions; and upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, adjusting at least one plasma generation parameter to mitigate formation of the plasma instability.
 2. The method for plasma processing of the wafer as recited in claim 1, wherein the plasma instability is a plasmoid characterized by an area of higher density plasma surrounded by larger volumes of normal density plasma.
 3. The method for plasma processing of the wafer as recited in claim 1, further comprising: supplying a process gas to the plasma generation region, the process gas being excited by radiofrequency power emanating from the electrode to generate the plasma within the plasma generation region.
 4. The method for plasma processing of the wafer as recited in claim 3, further comprising: controlling a pressure within the plasma generation region within a range extending from about 1 Torr to about 3 Torr.
 5. The method for plasma processing of the wafer as recited in claim 4, further comprising: controlling a distance as measured perpendicularly between the wafer support apparatus and the electrode to be within a range extending from about 0.3 inch to about 0.5 inch.
 6. The method for plasma processing of the wafer as recited in claim 1, wherein the optical signature of the plasma instability exhibits an increase in a ratio of a number of excited ions of a process gas to a number of excited neutral atoms of the process gas.
 7. The method for plasma processing of the wafer as recited in claim 1, wherein analyzing the collected optical emissions includes determining an intensity of optical emission corresponding to excited neutral atoms of a process gas, wherein the process gas is excited by radiofrequency power emanating from the electrode to generate the plasma within the plasma generation region, determining an intensity of optical emission corresponding to excited ions of the process gas, determining an indicator ratio of the intensity of optical emission corresponding to excited ions of the process gas to the intensity of optical emission corresponding to excited neutral atoms of the process gas, and determining whether or not the indicator ratio has increased by a threshold amount so as to indicate that the plasma instability does exist in the collected optical emissions.
 8. The method for plasma processing of the wafer as recited in claim 7, wherein the threshold amount is at least 3, or wherein the threshold amount is at least 5, or wherein the threshold amount is at least 7, or wherein the threshold amount is at least 9, or wherein the threshold amount is at least
 10. 9. The method for plasma processing of the wafer as recited in claim 7, wherein the process gas is argon, and wherein the intensity of optical emission corresponding to excited neutral atoms of the process gas is determined at a wavelength of about 750 nanometers, and wherein the intensity of optical emission corresponding to excited ions of the process gas is determined at a wavelength of about 480 nanometers.
 10. The method for plasma processing of the wafer as recited in claim 1, wherein analyzing the collected optical emissions to determine whether or not the optical signature of the plasma instability exists in the collected optical emissions is done following completion of the plasma processing of the wafer in which the optical emissions were collected.
 11. The method for plasma processing of the wafer as recited in claim 1, wherein analyzing the collected optical emissions to determine whether or not the optical signature of the plasma instability exists in the collected optical emissions is done in real-time during the plasma processing of the wafer in which the optical emissions were collected.
 12. The method for plasma processing of the wafer as recited in claim 11, further comprising: upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, reducing an amount of radiofrequency power supplied to the electrode.
 13. The method for plasma processing of the wafer as recited in claim 11, further comprising: upon determining that the optical signature of the plasma instability does not exist in the collected optical emissions, increasing an amount of radiofrequency power supplied to the electrode.
 14. The method for plasma processing of the wafer as recited in claim 1, further comprising: operating a direct current power supply to supply electrical current to the wafer support apparatus and from the wafer support apparatus directly to an underside of the wafer during plasma processing of the wafer.
 15. The method for plasma processing of the wafer as recited in claim 14, further comprising: upon determining that the optical signature of the plasma instability does exist in the collected optical emissions, increasing an amount of the electrical current supplied by the direct current power supply to the wafer support apparatus to mitigate formation of the plasma instability during plasma processing of the wafer.
 16. A system for plasma processing of a wafer, comprising: a wafer support apparatus configured to support a wafer during a plasma processing operation; an electrode positioned above the wafer support apparatus so as to form a plasma generation region between the electrode and the wafer support apparatus; a radiofrequency power supply connected to deliver radiofrequency power to the electrode; at least one optical emission collection device disposed to collect optical emissions from a plasma to be generated within the plasma generation region; and an optical signal processing unit configured to analyze optical emissions collected by the at least one optical emission collection device to determine whether or not an optical signature of a plasma instability exists in the collected optical emissions, the optical signal processing unit configured to provide notification of determining that the optical signature of the plasma instability does exist in the collected optical emissions.
 17. The system for plasma processing of the wafer as recited in claim 16, wherein the at least one optical emission collection device is one or more optical fibers extending from a position exposed to the plasma generation region to the optical signal processing unit.
 18. The system for plasma processing of the wafer as recited in claim 16, wherein the at least one optical emission collection device includes a charge coupled device camera positioned to view the plasma generation region, the charge coupled device camera connected to transmit signals representing the optical emissions collected from the plasma to the optical signal processing unit.
 19. The system for plasma processing of the wafer as recited in claim 16, further comprising: a process gas supply configured to supply a process gas to the plasma generation region, and wherein the optical signal processing unit is configured to determine an intensity of optical emission corresponding to excited neutral atoms of the process gas when the process gas is excited by radiofrequency power emanating from the electrode to generate the plasma within the plasma generation region, and wherein the optical signal processing unit is configured to determine an intensity of optical emission corresponding to excited ions of the process gas, and wherein the optical signal processing unit is configured to determine an indicator ratio of the intensity of optical emission corresponding to excited ions of the process gas to the intensity of optical emission corresponding to excited neutral atoms of the process gas, and wherein the optical signal processing unit is configured to determine whether or not the indicator ratio has increased by a threshold amount so as to indicate that the plasma instability does exist in the collected optical emissions.
 20. The system for plasma processing of the wafer as recited in claim 19, wherein the process gas is argon, and wherein the optical signal processing unit is configured to determine the intensity of optical emission corresponding to excited neutral atoms of the process gas at a wavelength of about 750 nanometers, and wherein the optical signal processing unit is configured to determine the intensity of optical emission corresponding to excited ions of the process gas at a wavelength of about 480 nanometers.
 21. The system for plasma processing of the wafer as recited in claim 16, further comprising: a feedback connection between the optical signal processing unit and the radiofrequency power supply, the optical signal processing unit configured to generate and transmit control signals through the feedback connection to control the radiofrequency power supply based on the determination of whether or not the optical signature of the plasma instability exists in the collected optical emissions.
 22. The system for plasma processing of the wafer as recited in claim 16, further comprising: a direct current power supply electrically connected to supply electrical current to the wafer support apparatus and directly to an underside of the wafer to be supported on the wafer support apparatus during plasma processing of the wafer; and a feedback connection between the optical signal processing unit and the direct current power supply, the optical signal processing unit configured to generate and transmit control signals through the feedback connection to control the direct current power supply based on the determination of whether or not the optical signature of the plasma instability exists in the collected optical emissions.
 23. The system for plasma processing of the wafer as recited in claim 22, wherein the feedback connection between the optical signal processing unit and the direct current power supply is a first feedback connection, the system also including a second feedback connection between the optical signal processing unit and the radiofrequency power supply, the optical signal processing unit configured to generate and transmit control signals through the second feedback connection to control the radiofrequency power supply based on the determination of whether or not the optical signature of the plasma instability exists in the collected optical emissions. 